SOF4 - Sulfur Monoxide Tetrafluoride:

First draw the lewis structure:
SOF4 Lewis Structure
Electron geometry: trigonal bipyramidal. Hybridization: sp3d

Second determine the 3D molecular geometry with VSEPR rules:
  Click and drag the molecle to rotate it.

Decision:
The molecular geometry of SOF4 is trigonal bipyramidal with asymmetric charge distribution around the central atom.
Therefore SOF4 is polar.

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