SO2Cl2 - Sulfuryl Chloride:
First draw the Lewis dot structure:
Electron geometry: tetrahedral. Hybridization: sp3
Then draw the 3D molecular structure using VSEPR rules:
Decision:
The molecular geometry of SO2Cl2 is tetrahedral with an asymmetric charge distribution on the central atom.
Therefore this molecule is polar.
Sulfuryl Chloride on Wikipedia.
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