PF3Cl2 - Phosphorus Trifluoride Dichloride:

First draw the Lewis dot structure:
PF3Cl2 Lewis Structure
Electron geometry: trigonal bipyramidal. Hybridization: sp3d

Then draw the 3D molecular structure using VSEPR rules:
Don't put the chlorine atoms directly across from each other;
the fluorine atoms are more electronegative than chlorine and will repel each other more strongly.

Click and drag the molecle to rotate it.

Decision:
The molecular geometry of PF3Cl2 is trigonal bipyramidal with asymmetric charge distribution on the central atom.
Therefore PF3Cl2 is polar.

This is somewhat of a rare molecule, but here is one similar:
Phosphorus Pentafluoride on Wikipedia.
Back to Molecular Geometries & Polarity Tutorial: Molecular Geometry & Polarity Tutorial.
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